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access, excess

Which should you use, access or excess? The noun access may mean the right to use something or the method of getting to a place. The noun excess means an amount more than necessary.

Incorrect: A solution is acidic when it has an access of hydronium ions.
Correct: A solution is acidic when it has an excess of hydronium ions.
Incorrect: You do not have excess to these files.
Correct: You do not have access to these files.
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